| Posted by Joe Fjelstad on 29 August 2006 at 14:13
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(This column, which originally appeared in Global SMT & Packaging magazine 6.6 (June/July 2006), is also available as a free PDF.)
While the
US
prepares for festivities marking another 4th of July celebration,
the EU will be embarking on its new Restriction of Hazardous Substances (RoHS)
adventure. This well intended but now clearly misguided piece of legislation
that was designed to make the environment better has slowly but surely been shown
to be anything but ‘green’, mostly because of its stance relative to lead in
electronic solders. Lead-free electronics has become the major sticking point
in this otherwise somewhat reasonable piece of legislation that also restricts
the use of a number of naturally occurring elements including cadmium,
hexavalent chrome and mercury along with some organic compounds (PBB and PBDE) commonly
used as flame retardants in plastics and laminates, which have been shown to
have possible links to cancer. Unfortunately, most of the campaign has been
carried out under the flag of lead-free, perhaps because lead has been so widely vilified in the press
as a poison that preferentially targets children, or perhaps because the
removal of lead from electronic solders was the most visible and would have the
greatest impact both industrially and economically; yet in truth, lead in
electronic solders accounts for less than ˝ of 1% of all lead used globally on
an annualized basis.
As this represents the last time that this column can make
the case before the law kicks in, it will recount again the reasons why lead in
electronic solders should be exempted from the RoHS provisions. First and
foremost are the environmental arguments against the ban of lead in electronic
solders. To that end, one should know that lead in electronic solder has never
been documented to have caused a single individual any harm from normal use.
Moreover, lead from electronic solders that does wind up in landfills does not
leach into ground water. Even with years of legacy lead from many other sources,
such as batteries and painted structures, all but a few (~3) landfills with
waste comprised of significant quantities of lead deposited from nearby head
lead use industries. Several studies from both universities and the US EPA have
indicated that on the whole, lead-free
electronics appear to be much less environmentally friendly. The primary
negative of lead is its toxicity, which for lead, as metal or in an alloy, is
highly unlikely to cause harm.
Considering now the alternatives being adopted, most
lead-free solders contain substantial percentages of silver (~ 3 to 4%) and
silver is toxic to microbial life and fish larva. Silver is thus a toxic real
risk. Add to that the fact that lead-free solders typically require
significantly higher temperatures to solder meaning that more energy is required
and will be consumed on a continuing basis adding unnecessarily to global
warming. Then there is the fact that tin use, will increase, while tin
resources are significantly lower than those of lead. This means that new tin
mining will likely be required. Unfortunately, some of the richest tin mines
are in rain forests, which will likely be clear cut to get to the tin deposits.
Turning attention to the economics of lead-free (other than
wasted energy cited above). The conversion cost, it has been calculated, will
likely run into the several tens of billions of dollars and could top 100
billion while the environment is made worse. (How many ways might that money be
better spent?) The reliability of lead-free solders is still a big uncertainty and
concern among reliability experts. There are still numerous effects (voiding,
tin whiskers, etc.) whose causes are neither well understood nor predictable. As
evidence, some products converted to lead-free are reportedly already running
return rates 3% to 4% higher than products that were soldered using traditional
solders. Return costs are 10 to 50 even 100 times greater than catching the
defect before it reaches the market. Moreover as one reliability sage observed,
“Reliability is best measured not by the return of the product but by the
return of the customer.” Additionally, traditional tin-lead solders will
continue to be used by military and aerospace manufacturers who must have the
highest levels of reliability, resulting in a dual path which will create ongoing
logistical headaches. Then there is the matter of product innovation will
continue to be delayed as engineers are diverted from solving real
technological problems associated with product development to solving a ‘problem’
that never actually existed in the opinion of most scientists.
Clearly there are compelling and persuasive arguments to be
made in favor of traditional tin-lead solders and nothing that can be argued
against it beyond blind emotionalism. But perhaps the most compelling argument
is being made by the EU’s other mandate, Waste Electrical and Electronic
Equipment (WEEE), the provisions of which mandate the recycling of electronic
products, making all of the concerns of lead in electronic solders completely
moot.
Wanting to end on a positive note, there is a strong
grassroots movement afoot to ‘push back’ on the lead-free portion of
legislation in favor of the environment. The Push back
website (www.rohsusa.com) has links to a
myriad of references which substantiate the arguments made here. Moreover,
there are signs of willingness on the part of some EU legislators to listen to
scientific evidence that lead-free solders represent a greater risk. This is
heartening news. When all is said and done, there will always remain the
simple unvarnished truth about this matter. Fortunately, the truth is as
perennial as the grass and has a way of continually popping back up no matter fiercely
one might try to keep it down.
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